The error regarding the wrong absolute path names is related to the prebuilt modules
prebuilt\64-bit-little-endian\ice-9\boot-9.go
prebuilt\32-bit-little-endian\ice-9\boot-9.go

They have been built with system-file-name-convention set to posix. In fact on mingw-w64 this value is set to windows. I forced
recompilation of related modules by
touch module\ice-9\boot-9.scm

For i686 the compilation process succeeded, for x86_64 recompilation of modules depending on boot-9 failed.

I recommend not to compile the posix/windows setting of  system-file-name-convention into the prebuilt modules in boot-9.scm:
(compile-time-case (system-file-name-convention) ...

Instead it could be evaluated during runtime. Otherwise formally different prebuilts are required, e.g.:  
prebuilt\64-bit-little-endian-posix
prebuilt\32-bit-little-endian-posix
prebuilt\64-bit-little-endian-windows
prebuilt\32-bit-little-endian-windows